本季中，绿箭侠和他的侠客团队，使斯塔林城的犯罪率降到了历史最低值。Oliver感觉自己终于可以在“绿箭侠”和“Oliver Queen”两种身份之间找到平衡点，终于可以过正常人的生活。于是他主动邀请Felicity出去约会。然而当一个新坏蛋打着已经死亡的“Vertigo伯爵”的招牌作案时，Olive...r陷入一种始料未及的糟糕情况，他身边十分亲密的某人严重受伤。Oliver决定与最近刚刚获得一身超级英雄制服的Roy联手制服这个新“伯爵”。与此同时，Diggle当上了父亲，Lance晋升为警司，专门用来追捕“兜帽侠客”的调查组被解散了，Laurel正式加入绿箭侠团队的核心圈子，Felicity在一家电子产品商店找了一份兼职工作来补贴家用。另一方面，Oliver尽全力恢复对Queen家族企业集团的控制，但一个十分有钱的竞争对手出现了——长相迷人的、让Felicity怦然心动的Ray Palmer。
Felicity等人被关在毒气室，闪电侠前来救援。Nyssa和绿箭侠混上忍者大师的飞机阻止其运输病毒，忍者大师携带降落伞逃生，绿箭侠拼尽全力使飞机迫降。绿箭团队全城追查忍者大师，Felicity发现其投毒的目标是斯塔灵大坝。绿箭侠与忍者大师对决最终手刃敌人，Felicity穿着原子侠服装紧急救援绿箭侠。Oliver决定放弃绿箭…
：This Is Your Sword
Oliver偷偷出去约见Malcolm，原来Oliver是假装被洗脑。Malcolm将Oliver潜伏的计划告知众人，Felicity却不相信。Maseo的妻子Tatsu出现表示愿意参与计划，她以自身的经历劝Felicity珍惜爱人。众人前往南达尔巴特追查携带毒气的飞机，一场恶战一触即发。原子侠将飞机击毁，Maseo终于如愿死在了自己的妻子Tatsu的手上…
：Al Sah-Him
Oliver在南达尔巴特受迷药洗脑，他可以轻易向亲人痛下杀手。Laurel无意间向Nyssa透露Oliver的状况，Nyssa坦白自己会变成Oliver的暗杀对象。果然，Oliver带领部下前来暗杀Nyssa，绿箭侠团队的众人都奋力保护Nyssa。而Oliver却挟持Diggle的妻子用来交换Nyssa，他成功劫走Nyssa还欲杀死Diggle，幸亏Thea及时…
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